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Beilstein J. Org. Chem. 2022, 18, 1159–1165, doi:10.3762/bjoc.18.120
Graphical Abstract
Scheme 1: Structures of hangtaimycin (1) and its co-metabolites.
Scheme 2: First synthetic route towards TDD (4).
Figure 1: HPLC analyses of (Z)-4 on a chiral stationary phase. A) Nearly racemic 4 from the first synthetic r...
Scheme 3: Second synthetic route towards TDD ((Z)-4).
Figure 2: X-ray structure of (rac)-4.
Figure 3: Bioactivity testing with hangtaimycin (1). A) Growth retardation of model species B. subtilis 168 a...
Beilstein J. Org. Chem. 2016, 12, 2164–2172, doi:10.3762/bjoc.12.206
Figure 1: The structures of marginolactones azalomycin and kanchanamycin, and of the β-lactones ebelactone A ...
Scheme 1: Comparison of the bioinformatic prediction for ebelactone biosynthesis with the known structure of ...
Scheme 2: Proposed model for iteration of module 1 of AzlA1 in azalomycin biosynthesis. The 4-guanidinobutyry...
Figure 2: LC–MS analysis of azalomycin F4a production. a) DSM4137 wild type; b) Δazl (azl disrupted mutant); ...